We can arrange the given compound in order of increasing boiling point as CO2 <CH3Br <CH3OH <RbF.
The compound with the highest boiling point is RbF, since it has the strongest intermolecular force.
CH3OH, CH3Br can doesn't posses strong intermolecular force compare to RbF, and they can form hydrogen bond.
CO2 can form weak dispersion force and it's a non polar compound and it posses the boiling point.
This is the temperature at whereby the vapor pressure of a liquid equals the pressure.
At this temperature, the liquid changes into a vapor and the weaker the force of attraction the lower the boiling point.
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